导读:英语翻译Since optical nonlinearity is caused by electronic polar 英语翻译Since optical nonlinearity is caused by electronic polarizabilityof materials on exposure to intense light beams,electronic p...
英语翻译Since optical nonlinearity is caused by electronic polar
英语翻译
Since optical nonlinearity is caused by electronic polarizability
of materials on exposure to intense light beams,
electronic polarizability is one of the most important
properties that govern the nonlinear response of the
materials.From Table 1,we can see that conventional
oxide glasses with a high optical elctronegativity possess low
polarizability and optical basicity.Tellurite and titanate
glasses,as well as borate glasses containing a large amount
of Sb2O3 and Bi2O3 with a low optical electronegativity,
show large polarizability and optical basicity.Hence the
glasses containing a heavy metal oxide possess a large linear
refractive index and NLO susceptibility [10].This is due to
the highly polarizable oxide ions in the heavy metal glasses
and the high polarizability of their cations,and this leads to
a high polarizability of the whole molecule and easy
distortions of the electron density in a strong electromagnetic
field.It has been established that third order NLO
susceptibility of binary oxide glasses increases with decreasing
optical electronegativity.
The inclusion of optical electronegativity Dw2glass has a
direct bearing on the concept of chemical bonding [20].The
magnitude of optical electronegativity Dw2glass indicates the
nature of bonding in the materials.If the optical
electronegativity Dw2glass is high,the materials are considered
ionic in nature and if its magnitude is less,the
materials are considered to be covalent in nature.It is also
noticed that for molecules whose optical electronegativity
Dw2 value is less,their refractive index n,electronic
polarizability aO23 ,and optical basicity L are high.From
this study it is possible to correlate the electronic
polarizability aO23 with the optical basicity L,refractive
index n,and the nature of bonding of materials.
3.Conclusions
In this paper,we introduce the optical electronegativity
Dw2glass,to predict basic properties of binary oxide glasses
(phosphate,borate,silicate,germinate,tellurite,and
titanate).Estimations of refractive index n,energy gap
Eg,average electronic oxide polarizability aO23 ,and optical
basicity L on the basis of the optical electronegativity
Dw2glass is a new method and the results are in reasonable
agreements with the results of literature.Hence this
approach may also be used as one of the alternative
methods to estimate the optical basicity L,average
electronic oxide polarizability aO23 and refractive index n
of binary oxide glasses.
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由于非线性光学性质,是造成电子极化
材料,暴露于激烈的光束,
电子极化是其中最重要的
物业管非线性响应的
材料.从表1中,我们可以看到,常规
氧化物玻璃具有高光学elctronegativity具备低
极化和光学碱度.碲和钛
眼镜,以及硼酸盐玻璃含有大量
对Sb2O3的和氧化铋与低光电,
显示大极化和光学碱度.因此,
眼镜含有重金属氧化物拥有庞大的线性
折射率和非线性光学易感性[ 10 ] .这是由于
高度极化氧化物离子在重金属眼镜
和高极化其阳离子,这导致
高极化整个分子和容易
扭曲的电子密度,在强电磁
领域.已确定的三阶非线性光学
易感性的二元氧化物玻璃的增加与减少
光学电.
列入光学电DW的玻璃有一个
直接关系的概念,化学键[ 20 ] .那个
规模光学电DW的玻璃显示
的性质,结合在材料.如果光
电DW的玻璃是高,材料被认为是
离子的性质,如果其规模较小,
材料被认为是共价键的性质.这也是
注意到,为分子,其光学电
DW的价值是少,其折射率n ,电子
极化ao2 ,及光学碱度升高.自
这项研究是有可能的关联电子
极化ao2与光学碱度升,屈光
指数n ,和性质的粘接材料.
3 .结论
在本文中,我们引入光学电
DW的玻璃,预测的基本性质二元氧化物玻璃
(磷酸盐,硼酸盐,硅酸盐,发芽,碲,
钛酸) .估计折射率n ,能源的差距
例如,平均电子氧化氮极化ao2 ,及光学
碱度升的基础上的光学电
DW的玻璃是一种新的方法和结果是在合理的
协议的结果,文学作品.因此,这
办法也可能被用来作为一个替代
估计方法的光学碱度升,平均
电子氧化氮极化ao2和折射率n
二元氧化物玻璃.
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